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- W2068668812 abstract "Paramagnetic cluster ions of the type Cu(II)6Cu(I)8L12Clz, where z is charge and L a derivative of 1-amino-2,2-dimethyl-2-mercaptoethane, have been shown to produce detectable 1H-nmr absorptions. Linewidths are narrow enough to permit the use of high resolution instruments. Downfield shifting of all detectable resonances is indicative of S → Cu2+ charge transfer, which results in a positive spin density at sulfur. Exchange measurements with 67Cu indicate relatively static structures." @default.
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- W2068668812 date "1978-01-01" @default.
- W2068668812 modified "2023-09-24" @default.
- W2068668812 title "The 1H-nmr spectra of mixed valence complexes of copper with derivatives of 1-amino-2,2-dimethyl-2-mercaptoethane" @default.
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- W2068668812 doi "https://doi.org/10.1016/s0006-3061(00)80242-2" @default.
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