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- W2068673926 abstract "The hydrolysis of the title compound proceeds very fast in weakly acidic aqueous media by a stepwise release of both ethyl ester groups via phosphorus-oxygen bond fission. The reactions are about 106 times faster than that for the release of one ethyl group of the corresponding trans-isomer. The observed kinetics are consistent with a mechanism involving intramolecular catalysis by the undissociated carboxyl group." @default.
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- W2068673926 date "2010-09-02" @default.
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- W2068673926 title "Intramolecular catalysis in cis-diethyl 2-carboxyvinylphosphonate hydrolysis" @default.
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- W2068673926 doi "https://doi.org/10.1002/recl.19740930204" @default.
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