FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2068674916> ?p ?o ?g. }

• W2068674916 endingPage "1369" @default.
• W2068674916 startingPage "1361" @default.
• W2068674916 abstract "We wish to report the synthesis, crystal structures, spectroscopic and electrochemical properties of new Pt(II) heteroleptic complexes with two diimines (2,2′-bipyridine, 4,4′-dimethyl-2,2′-bipyridine), and the crown trithioether 9S3 (1,4,7-trithiacyclononane). In addition, we report the synthesis and spectroscopic properties of three related 9S3/diimine (4,4′-di-t-butyl-2,2′-bipyridine, 4,4′-dinonyl-2,2′-bipyridine, 3,4,7,8-tetramethyl-1,10-phenanthroline) complexes as well as an examination of the spectroscopic and electrochemical properties of the reported [Pt(9S3)(1,10-phenanthroline)](PF6)2. All complexes have the general formula [Pt(9S3)(N2)](PF6) (N2 = diimine) and form similar structures in which the Pt(II) center is surrounded by a cis arrangement of the two N donors from the diimine chelate and two sulfur atoms from the 9S3 ligand. The 195Pt NMR chemical shifts for all six complexes show a value near −3290 ppm, consistent with a cis-PtS2N2 coordination sphere. The third sulfur in each structure forms a longer interaction with the platinum resulting in an elongated square pyramidal structure. These distances, however, are approximately 0.2 Å longer than with the analogous diphosphine complexes, demonstrating that better π acids, in fact, do not result in shorter Pt–S axial distances as has previously been proposed." @default.
• W2068674916 created "2016-06-24" @default.
• W2068674916 creator A5015420701 @default.
• W2068674916 creator A5035192727 @default.
• W2068674916 creator A5039099478 @default.
• W2068674916 creator A5059588554 @default.
• W2068674916 creator A5071299605 @default.
• W2068674916 creator A5085317860 @default.
• W2068674916 date "2004-05-01" @default.
• W2068674916 modified "2023-10-13" @default.
• W2068674916 title "Heteroleptic platinum(II) complexes with crown thioethers and diimine ligands: the crystal structures of [Pt(9S3)(2,2′-bipy)](PF6)2 and [Pt(9S3)(4,4-dimethyl-2,2′-bipy)](PF6)2·2.5CH3NO2" @default.
• W2068674916 cites W1518610497 @default.
• W2068674916 cites W1868033639 @default.
• W2068674916 cites W1919416664 @default.
• W2068674916 cites W1967590443 @default.
• W2068674916 cites W1970752952 @default.
• W2068674916 cites W1973585132 @default.
• W2068674916 cites W1976370018 @default.
• W2068674916 cites W1978289430 @default.
• W2068674916 cites W1985148318 @default.
• W2068674916 cites W2001993329 @default.
• W2068674916 cites W2002031369 @default.
• W2068674916 cites W2011625287 @default.
• W2068674916 cites W2014188599 @default.
• W2068674916 cites W2015804422 @default.
• W2068674916 cites W2017556186 @default.
• W2068674916 cites W2036564716 @default.
• W2068674916 cites W2041922265 @default.
• W2068674916 cites W2046579873 @default.
• W2068674916 cites W2076408787 @default.
• W2068674916 cites W2077209971 @default.
• W2068674916 cites W2078078462 @default.
• W2068674916 cites W2114349790 @default.
• W2068674916 cites W2128590724 @default.
• W2068674916 cites W2136551396 @default.
• W2068674916 cites W2144332006 @default.
• W2068674916 cites W2171344754 @default.
• W2068674916 cites W28544235 @default.
• W2068674916 doi "https://doi.org/10.1016/j.poly.2004.02.023" @default.
• W2068674916 hasPublicationYear "2004" @default.
• W2068674916 type Work @default.
• W2068674916 sameAs 2068674916 @default.
• W2068674916 citedByCount "28" @default.
• W2068674916 countsByYear W20686749162012 @default.
• W2068674916 countsByYear W20686749162013 @default.
• W2068674916 countsByYear W20686749162014 @default.
• W2068674916 countsByYear W20686749162015 @default.
• W2068674916 countsByYear W20686749162019 @default.
• W2068674916 crossrefType "journal-article" @default.
• W2068674916 hasAuthorship W2068674916A5015420701 @default.
• W2068674916 hasAuthorship W2068674916A5035192727 @default.
• W2068674916 hasAuthorship W2068674916A5039099478 @default.
• W2068674916 hasAuthorship W2068674916A5059588554 @default.
• W2068674916 hasAuthorship W2068674916A5071299605 @default.
• W2068674916 hasAuthorship W2068674916A5085317860 @default.
• W2068674916 hasConcept C115624301 @default.
• W2068674916 hasConcept C116569031 @default.
• W2068674916 hasConcept C147789679 @default.
• W2068674916 hasConcept C161790260 @default.
• W2068674916 hasConcept C170493617 @default.
• W2068674916 hasConcept C17525397 @default.
• W2068674916 hasConcept C178790620 @default.
• W2068674916 hasConcept C179104552 @default.
• W2068674916 hasConcept C185592680 @default.
• W2068674916 hasConcept C197404232 @default.
• W2068674916 hasConcept C2776303508 @default.
• W2068674916 hasConcept C2779336533 @default.
• W2068674916 hasConcept C518104683 @default.
• W2068674916 hasConcept C518881349 @default.
• W2068674916 hasConcept C52859227 @default.
• W2068674916 hasConcept C55493867 @default.
• W2068674916 hasConcept C71240020 @default.
• W2068674916 hasConcept C8010536 @default.
• W2068674916 hasConceptScore W2068674916C115624301 @default.
• W2068674916 hasConceptScore W2068674916C116569031 @default.
• W2068674916 hasConceptScore W2068674916C147789679 @default.
• W2068674916 hasConceptScore W2068674916C161790260 @default.
• W2068674916 hasConceptScore W2068674916C170493617 @default.
• W2068674916 hasConceptScore W2068674916C17525397 @default.
• W2068674916 hasConceptScore W2068674916C178790620 @default.
• W2068674916 hasConceptScore W2068674916C179104552 @default.
• W2068674916 hasConceptScore W2068674916C185592680 @default.
• W2068674916 hasConceptScore W2068674916C197404232 @default.
• W2068674916 hasConceptScore W2068674916C2776303508 @default.
• W2068674916 hasConceptScore W2068674916C2779336533 @default.
• W2068674916 hasConceptScore W2068674916C518104683 @default.
• W2068674916 hasConceptScore W2068674916C518881349 @default.
• W2068674916 hasConceptScore W2068674916C52859227 @default.
• W2068674916 hasConceptScore W2068674916C55493867 @default.
• W2068674916 hasConceptScore W2068674916C71240020 @default.
• W2068674916 hasConceptScore W2068674916C8010536 @default.
• W2068674916 hasIssue "8" @default.
• W2068674916 hasLocation W20686749161 @default.
• W2068674916 hasOpenAccess W2068674916 @default.
• W2068674916 hasPrimaryLocation W20686749161 @default.
• W2068674916 hasRelatedWork W1969166519 @default.
• W2068674916 hasRelatedWork W1998558127 @default.
• W2068674916 hasRelatedWork W2008962678 @default.

• next