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- W2068676719 abstract "The low-temperature Evans−Tishchenko coupling of a range of functionalized heteroaryl aldehydes with β-hydroxy ketones in the presence of a Sm(III) catalyst has been achieved with high yields (90−99%) and good to excellent diastereoselectivity (90:10 → 95:5 dr). However, at room temperature a retro-aldol aldol-Tishchenko reaction was found to compete with the desired Evans−Tishchenko reaction. Identification of these byproducts has allowed the corresponding aldol-Tishchenko reaction to be optimized for several heteroaryl aldehydes." @default.
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- W2068676719 date "2010-10-07" @default.
- W2068676719 modified "2023-09-26" @default.
- W2068676719 title "Evans−Tishchenko Coupling of Heteroaryl Aldehydes" @default.
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- W2068676719 doi "https://doi.org/10.1021/jo1015689" @default.
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