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- W2068704140 abstract "Rates of solvolysis of complex ions [Co(3Rpy)4Cl2]+ with R = Me and Et have been determined in mixtures of water with t-butyl alcohol over a range of temperatures. Extrema found in the enthalpy ΔH* and entropy ΔS* of activation are correlated with the physical properties of the solvent mixtures which are influenced by changes in the solvent structure and these extrema are compared with those found for the solvolysis of related complexes in water + alcohol mixtures. Isokinetic plots over wide ranges of ΔH* and ΔS* are compared for the solvolysis of CoIII complexed to a variety of ligands. The application of a free energy cycle shows that the emergent cobalt (III) cation in the transition state becomes increasingly stabilized in water-rich mixtures relative to the cobalt (III) cation in the initial state as the mol fraction of t-butyl alcohol increases." @default.
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- W2068704140 date "1992-06-01" @default.
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- W2068704140 title "Kinetics of the solvolysis of [Co(3Rpy)4Cl2]+ ions (R =Me orEt) in Water +t-butyl alcohol mixtures" @default.
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- W2068704140 doi "https://doi.org/10.1002/kin.550240606" @default.
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