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- W2068708367 abstract "Phosphine-mediated olefination between α-substituted allenoates and aldehydes to form 1,2,3,4-tetrasubstituted 1,3-dienes is presented. High levels of chemo- and diastereoselectivity and yield are obtained for a wide scope of substrates with the choice of appropriate phosphines. This reaction evidences the capacity of phosphines in the control of reaction pathways and provides a highly efficient synthetic method for tetrasubstituted conjugated dienes." @default.
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- W2068708367 date "2010-07-15" @default.
- W2068708367 modified "2023-10-05" @default.
- W2068708367 title "Stereoselective Synthesis of 1,2,3,4-Tetrasubstituted Dienes from Allenoates and Aldehydes: An Observation of Phosphine-Induced Chemoselectivity" @default.
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- W2068708367 doi "https://doi.org/10.1021/ol101429z" @default.
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