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- W2068715053 abstract "The charge transfer in low energy (0.25 to 150 eV/amu) H($nl$) + He$^+(1s)$ collisions is investigated using a quasi-molecular approach for the $n=2,3$ as well as the first two $n=4$ singlet states. The diabatic potential energy curves of the HeH$^+$ molecular ion are obtained from the adiabatic potential energy curves and the non-adiabatic radial coupling matrix elements using a two-by-two diabatization method, and a time-dependent wave-packet approach is used to calculate the state-to-state cross sections. We find a strong dependence of the charge transfer cross section in the principal and orbital quantum numbers $n$ and $l$ of the initial or final state. We estimate the effect of the non-adiabatic rotational couplings, which is found to be important even at energies below 1 eV/amu. However, the effect is small on the total cross sections at energies below 10 eV/amu. We observe that to calculate charge transfer cross sections in a $n$ manifold, it is only necessary to include states with $n^{prime}leq n$, and we discuss the limitations of our approach as the number of states increases." @default.
- W2068715053 created "2016-06-24" @default.
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- W2068715053 date "2010-07-26" @default.
- W2068715053 modified "2023-10-14" @default.
- W2068715053 title "<i>Ab initio</i>calculation of<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mrow><mml:mi mathvariant=normal>H</mml:mi><mml:mo>+</mml:mo><mml:msup><mml:mi mathvariant=normal>He</mml:mi><mml:mrow><mml:mo>+</mml:mo></mml:mrow></mml:msup></mml:mrow></mml:math>charge-transfer cross sections for plasma physics" @default.
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- W2068715053 doi "https://doi.org/10.1103/physreva.82.012708" @default.
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