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- W2068731186 abstract "Abstract Two isomorphous compounds [Eu(2,2′-bpdc)(NO3)(e-urea)3]n (1) and [Tb(2,2′-bpdc)(NO3)(e-urea)3]n (2) (2,2′-bpdc2 − = 2,2′-biphenyldicarboxylate and e-urea = ethyleneurea) have been synthesized using a deep-eutectic solvent of choline chloride/e-urea. The lanthanide ions are linked by the 2,2′-bpdc2 − ligands to form one-dimensional helical chains in these compounds. Of special interest is the presence of parallel left- and right-handed single helices with the ratio of 1:1 in both compounds. Detailed photoluminescence studies show that both compounds exhibit typical lanthanide luminescent emissions and the excitation energy has been efficiently transferred to the lanthanide ions from the organic ligands." @default.
- W2068731186 created "2016-06-24" @default.
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- W2068731186 date "2014-08-01" @default.
- W2068731186 modified "2023-10-17" @default.
- W2068731186 title "Two lanthanide coordination polymers with helical chain structures synthesized ionothermally from a deep-eutectic solvent: syntheses, structures and luminescence" @default.
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- W2068731186 doi "https://doi.org/10.1016/j.inoche.2014.06.021" @default.
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