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- W2068742871 abstract "The crystal structure of the title compound, [Co(C9H13N5)2] I2,H2O, has been determined by single-crystal X-ray diffraction at 295 K and refined by least squares to a residual of 0.058 for 3255 'observed' reflections. Crystals are triclinic, Pī, a 14.934(5), b 11.315(4), c 8.090(3)Ǻ, α 85.19(3), β 87.76(3), γ 74.10(3)°, Z 2. The distances from the cobalt to the central trimethine nitrogen atoms are 1.893(8) and 1.903(8)Ǻ consistent with the almost low-spin behaviour of the complex; the distal Co-N distances range between 2.045(8) and 2.140(8)Ǻ. One of the iodide anions appears to be disordered over two sites populated in the ratio 0.86:0.14; occupancy of the second site together with the magnetic moment of 2.1 BM may indicate a small proportion of the high-spin isomer." @default.
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- W2068742871 date "1978-01-01" @default.
- W2068742871 modified "2023-10-14" @default.
- W2068742871 title "Crystal structure of Bis(2,6-diacetylpyridine dihydrazone)cobalt(II) diiodide monohydrate" @default.
- W2068742871 doi "https://doi.org/10.1071/ch9780737" @default.
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