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• W2068746845 startingPage "485" @default.
• W2068746845 abstract "The effective diffusion coefficients, D*, of three anions (Br-,Cl-, and I-) three cations Cd2+,K+, and Zn2+ diffusing in two compacted clay soils, kaolinite and Lufkin clay, are measured. The ions are contained in a simulated waste leachate. The effects of molding water content and method of compaction on the measured D* values are evaluated for kaolinite. The calculated D* values varied between 4×10-10m2/s and 2×10-9m2/s and, based on the results for chloride diffusion in kaolinite, are relatively insensitive to molding water content and compaction method. The measured D* values for Cl- and Br- in kaolinite are in excellent agreement with previous studies, but the D* values for the cations are relatively high. High D* values for the cations are attributed to nonlinear adsorption behavior at relatively high concentrations and to the possibility of chemical precipitation of the heavy metal species (Cd2+ and Zn2+). Also, D* values determined from reservoir concentrations typically are higher than D* values determined from soil concentration profiles." @default.
• W2068746845 created "2016-06-24" @default.
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• W2068746845 date "1991-03-01" @default.
• W2068746845 modified "2023-10-06" @default.
• W2068746845 title "Diffusion in Saturated Soil. II: Results for Compacted Clay" @default.
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• W2068746845 doi "https://doi.org/10.1061/(asce)0733-9410(1991)117:3(485)" @default.
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