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- W2068755916 abstract "La structure cristalline de Na3H(C2O4)2SbOF, 2H2O fait apparaître des anions SbOF(C2O4)24− dans lesquels les groupements oxalates sont des chélates bidendates sur l'antimoine III. La coordination de l'antimoine est de 7. Cinq atomes d'oxygène étant situés dans le plan de la bipyramide à base pentagonale, déformée par la paire électronique libre de SbIII située en position axiale, l'atome de fluor de l'oxyfluorure occupant l'autre position axiale. L'existence d'un ion oxonium est discutée. Crystal Structure of Na3H(C2O4)2SbOF, 2 H2O. On the Existence of the Pentagonal Bipyramid SbO5FE The crystal structure of Na3H(C2O4)2SbOF, 2H2O shows SbOF(C2O4)24− anions where oxalat units are bidendate chelates on the antimony (III). Antimony coordination is seven; five oxygen atoms are situated on the plane of the pentagonal bipyramid, distorded by the electronic lone pair of SbIII, situated in an axial position; the fluorine atom of the oxofluoride occupies the other axial position. The existence of an oxonium ion is discussed." @default.
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- W2068755916 date "1980-06-01" @default.
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- W2068755916 title "Structure Cristalline de Na3H(C2O4)2SbOF, 2 H2O. Existence de la Bipyramide � Base Pentagonale SbO5FE" @default.
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- W2068755916 doi "https://doi.org/10.1002/zaac.19804650104" @default.
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