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- W2068756719 abstract "Nitrogen chelating ligands (such as TMEDA) orientate the attack of silyl enolates on central allyl carbon of η3-allyl Pd complexes to yield cyclopropanes with remarkable regioselectivity. In presence of platinum complexes the regioselectivity of the reaction may be switched to either the central or terminal allyl carbons according to the coordinated ligand thus TMEDA yields allylation products, PCy3 mainly cyclopropanes." @default.
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- W2068756719 date "1993-10-01" @default.
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- W2068756719 title "Nucleophilic attack on the central allyl carbon of η3-allyl complexes of Pd and Pt. Synthesis of cyclopropanes from allylic electrophiles and silyl enolates" @default.
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- W2068756719 doi "https://doi.org/10.1016/0304-5102(93)85057-z" @default.
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