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• W2068761566 abstract "Photoelectron diffraction in the scanned-energy mode is now an accepted method in surface structural analysis. Here we demonstrate its use in the determination of the local adsorption geometry of the methoxy species CH3O- on a Ni(111) surface. The bonding site of the O atom at an “fcc” hollow site directly above a Ni atom in the third layer is obtained from the experimental data using direct methods, and the exact NiO spacing and degree of local substrate distortion, together with the molecular orientation, are found by the use of multiple scattering simulations. A re-analysis of earlier data obtained for the same species on Cu(111) confirms the results of this earlier study and has allowed an evaluation og possible subtle differences in the adsorbate-induced substrate distortion despite the occupation of the same adsorption site and very similar O-metal nearest neighbour distances." @default.
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• W2068761566 date "1995-12-01" @default.
• W2068761566 modified "2023-09-26" @default.
• W2068761566 title "Quantitative determination of molecular adsorption structures using photoelectron diffraction: the methoxy species" @default.
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• W2068761566 doi "https://doi.org/10.1016/0368-2048(95)02390-9" @default.
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