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• W2068762694 abstract "The reaction of Ni(acac)2·2H2O (acac = 2,4-pentanedionate, C5H7O−2 with Ph3AsO in ethanol yields the 2:1 complex [Ni(acac)2]2·Ph3AsO as the only products. Similar reactions with Co(acac)2· 2H2O yield mainly Co(acac)2·2Ph3AsO with a small amount of [Co(acac)2]2·Ph3AsO. The 2:1 complexes [M(acac)2]2·Ph3AsO are binuclear, isomorphous (space group P21/a, Z = 4) with three MOM bridges. One bridging oxygen atom belongs to the arsine oxide ligand; the other two come from pentanedionate ligands. The complex molecules are asymmetric. The orientation of the arsine oxide ligand. with the AsO bond bent sharply away from the bridging MOM plane (where O is the arsine oxide oxygen atom) suggests a strongly stereochemically active lone pair on the oxygen atom" @default.
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• W2068762694 date "1981-01-01" @default.
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• W2068762694 title "Complexes of bis(2,4-pentanedionato)nickel(II) and -cobalt(II) with triphenylarsine oxide. Crystal and molecular structures of bis[μ-(2,4-pentanedionato-O:O,O′)]bis(2,4-pentanedionato-O,O′[μ-(triphenylarsine oxide-O:O)]dinickel(II) and -dicobalt(II), [M(C5H7O2)2]2·Ph3AsO (M = Ni, Co)" @default.
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• W2068762694 doi "https://doi.org/10.1016/s0020-1693(00)90493-6" @default.
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