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• W2068763536 abstract "The mesomorphism of three series of compounds has been studied. Compounds in Series I [4-nitrobenzoic acid N′-(4′-n-alkoxybenzoyl)hydrazides] were synthesised by the Schotten–Baumann reaction of 4-nitrobenzhydrazide with 4-n-alkoxybenzoyl chloride in dry pyridine. The resulting compounds were cyclised using phosphoryl chloride to give bent-shaped mesogenic 2-(4′-nitrophenyl)-5-(4″-n-alkoxyphenyl)-1,3,4-oxadiazoles (Series II) or, using phosphorus pentasulphide, 2-(4′-nitrophenyl)-5-(4″-n-alkoxyphenyl)-1,3,4-thiadiazoles (Series III). These compounds have been characterised using a combination of elemental analysis and spectroscopic techniques. The mesomorphic properties of the three series were compared with one other and with other structurally related compounds. The effect of different heterocyclic moieties and terminal substituents on mesomorphism has been evaluated." @default.
• W2068763536 created "2016-06-24" @default.
• W2068763536 creator A5041676584 @default.
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• W2068763536 date "2011-02-17" @default.
• W2068763536 modified "2023-10-16" @default.
• W2068763536 title "Mesogenic bent-shaped nitrooxadiazoles and thiadiazoles" @default.
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• W2068763536 doi "https://doi.org/10.1080/02678292.2010.535659" @default.
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