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- W2068772648 abstract "A new cobalt aluminophosphate, CoxAl1-xPO4[(NH4)x(NH3)0.5-x], with relatively high cobalt content (x ≤ 0.4) has been hydrothermally synthesized and characterized by single-crystal X-ray diffraction, thermogravimetric analysis, and infrared and visible light spectroscopies. The structure of the compound is a new zeolite-like open framework (monoclinic, C2/c, Z = 4, a = 13.312(3), b = 13.160(3), c = 8.914(2) Å, β = 100.94(3)° for x = 0.38). It contains channels of eight-membered rings of alternating tetrahedra of (Co,Al)O4 and PO4. The templates of NH4+ and NH3 reside in the channels and are surrounded by oxygen atoms with N−O distances of 3.0 Å and above." @default.
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- W2068772648 date "1997-12-01" @default.
- W2068772648 modified "2023-09-23" @default.
- W2068772648 title "Synthesis and Characterization of a New Cobalt Aluminophosphate with an Open-Framework Structure" @default.
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- W2068772648 doi "https://doi.org/10.1021/cm9704544" @default.
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