Matches in SemOpenAlex for { <https://semopenalex.org/work/W2068786346> ?p ?o ?g. }
- W2068786346 endingPage "1590" @default.
- W2068786346 startingPage "1582" @default.
- W2068786346 abstract "Carbon-13 and nitrogen-15 nuclear magnetic resonance (NMR) spectra of solid copper(I) cyanide present a clear picture of its molecular structure as comprising linear, polymeric chains: [−Cu−N−C−]n. Copper-63/65 nuclear quadrupole resonance reveals that the cyanide ligands are subject to “head-tail” disorder. Magic-angle spinning NMR spectra are analyzed by accounting for the quadrupolar effects of neighboring copper nuclei to yield one-bond indirect spin−spin coupling constants, 1J(63Cu,13C) ≈ +725 Hz and 1J(63Cu,15N) ≈ −250 Hz, and effective dipolar coupling constants, Reff(63Cu,13C) ≈ +1200 Hz and Reff(63Cu,15N) ≈ −460 Hz. The dipolar coupling data correspond to internuclear separations of rCu,C ≈ 1.88 Å and rCu,N ≈ 1.92 Å. The observation of axially symmetric 15N and 13C chemical shielding tensors in NMR spectra of nonspinning samples provides compelling evidence for the structural linearity of CuCN chains. Conclusions based on experimental data are supported by ab initio calculations of chemical shielding and electric field gradients." @default.
- W2068786346 created "2016-06-24" @default.
- W2068786346 creator A5014487148 @default.
- W2068786346 creator A5018398572 @default.
- W2068786346 creator A5058851361 @default.
- W2068786346 date "1999-01-27" @default.
- W2068786346 modified "2023-10-06" @default.
- W2068786346 title "The Structure of Solid Copper(I) Cyanide: A Multinuclear Magnetic and Quadrupole Resonance Study" @default.
- W2068786346 cites W1662494019 @default.
- W2068786346 cites W1964664772 @default.
- W2068786346 cites W1965170786 @default.
- W2068786346 cites W1967416025 @default.
- W2068786346 cites W1967830614 @default.
- W2068786346 cites W1967959801 @default.
- W2068786346 cites W1969051580 @default.
- W2068786346 cites W1975095877 @default.
- W2068786346 cites W1977877711 @default.
- W2068786346 cites W1994363985 @default.
- W2068786346 cites W1996043738 @default.
- W2068786346 cites W1996138414 @default.
- W2068786346 cites W2004007929 @default.
- W2068786346 cites W2006796659 @default.
- W2068786346 cites W2008169289 @default.
- W2068786346 cites W2008340011 @default.
- W2068786346 cites W2011042375 @default.
- W2068786346 cites W2015540300 @default.
- W2068786346 cites W2016226337 @default.
- W2068786346 cites W2026105978 @default.
- W2068786346 cites W2029313674 @default.
- W2068786346 cites W2030446652 @default.
- W2068786346 cites W2031502207 @default.
- W2068786346 cites W2033288927 @default.
- W2068786346 cites W2046552363 @default.
- W2068786346 cites W2049554923 @default.
- W2068786346 cites W2054164390 @default.
- W2068786346 cites W2058254781 @default.
- W2068786346 cites W2060048911 @default.
- W2068786346 cites W2064047298 @default.
- W2068786346 cites W2067761434 @default.
- W2068786346 cites W2073617505 @default.
- W2068786346 cites W2078588308 @default.
- W2068786346 cites W2080145570 @default.
- W2068786346 cites W2135321529 @default.
- W2068786346 cites W2142048422 @default.
- W2068786346 cites W2156115804 @default.
- W2068786346 cites W2256495696 @default.
- W2068786346 cites W2950755836 @default.
- W2068786346 cites W2951320097 @default.
- W2068786346 cites W4247950783 @default.
- W2068786346 doi "https://doi.org/10.1021/ja983253p" @default.
- W2068786346 hasPublicationYear "1999" @default.
- W2068786346 type Work @default.
- W2068786346 sameAs 2068786346 @default.
- W2068786346 citedByCount "67" @default.
- W2068786346 countsByYear W20687863462012 @default.
- W2068786346 countsByYear W20687863462013 @default.
- W2068786346 countsByYear W20687863462015 @default.
- W2068786346 countsByYear W20687863462016 @default.
- W2068786346 countsByYear W20687863462017 @default.
- W2068786346 countsByYear W20687863462018 @default.
- W2068786346 countsByYear W20687863462019 @default.
- W2068786346 countsByYear W20687863462020 @default.
- W2068786346 countsByYear W20687863462021 @default.
- W2068786346 countsByYear W20687863462022 @default.
- W2068786346 countsByYear W20687863462023 @default.
- W2068786346 crossrefType "journal-article" @default.
- W2068786346 hasAuthorship W2068786346A5014487148 @default.
- W2068786346 hasAuthorship W2068786346A5018398572 @default.
- W2068786346 hasAuthorship W2068786346A5058851361 @default.
- W2068786346 hasConcept C111429119 @default.
- W2068786346 hasConcept C121332964 @default.
- W2068786346 hasConcept C1276947 @default.
- W2068786346 hasConcept C139210041 @default.
- W2068786346 hasConcept C147789679 @default.
- W2068786346 hasConcept C159985019 @default.
- W2068786346 hasConcept C178790620 @default.
- W2068786346 hasConcept C184779094 @default.
- W2068786346 hasConcept C185592680 @default.
- W2068786346 hasConcept C192562407 @default.
- W2068786346 hasConcept C2265751 @default.
- W2068786346 hasConcept C2778981401 @default.
- W2068786346 hasConcept C39984356 @default.
- W2068786346 hasConcept C46141821 @default.
- W2068786346 hasConcept C4839761 @default.
- W2068786346 hasConcept C544778455 @default.
- W2068786346 hasConcept C66974803 @default.
- W2068786346 hasConcept C67787023 @default.
- W2068786346 hasConcept C71240020 @default.
- W2068786346 hasConcept C77872520 @default.
- W2068786346 hasConcept C84935128 @default.
- W2068786346 hasConceptScore W2068786346C111429119 @default.
- W2068786346 hasConceptScore W2068786346C121332964 @default.
- W2068786346 hasConceptScore W2068786346C1276947 @default.
- W2068786346 hasConceptScore W2068786346C139210041 @default.
- W2068786346 hasConceptScore W2068786346C147789679 @default.
- W2068786346 hasConceptScore W2068786346C159985019 @default.
- W2068786346 hasConceptScore W2068786346C178790620 @default.
- W2068786346 hasConceptScore W2068786346C184779094 @default.