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- W2068788053 abstract "Abstract In the presence of a catalytic amount of cesium hydroxide under a nitrogen atmosphere, terminal alkynes reacted with diaryl disulfides at room temperature in dimethylformamide to give almost exclusively (Z)-1,2-diarylthio-1-alkene in good yields, but under an air atmosphere, the reaction gave a mixture of alkynyl sulfide and (Z)-1,2-diarylthio-1-alkene. Keywords: Cesium hydroxidediaryl disulfide(Z)-1,2-diarylthio-1-alkeneterminal alkyne ACKNOWLEDGMENTS Projects 20372020 and 02JJY4053 were supported by the National Nature Science Foundations of China and Hunan, respectively." @default.
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- W2068788053 date "2009-06-16" @default.
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- W2068788053 title "Stereoselective Synthesis of (Z)-1,2-Diarylthio-1-alkene via the Reaction of Diaryl Disulfides with Terminal Alkynes Catalyzed by Cesium Hydroxide" @default.
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- W2068788053 doi "https://doi.org/10.1080/00397910802654831" @default.
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