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- W2068792204 abstract "Lanthanoid metal (Ln) complexes of the types, [Ln(Hapnh)2Cl2]Cl·nH2O and [Ln(apnh)3] have been prepared by reacting 2-acetylpyridine nicotinoylhydrazone (abbreviated to Hapnh) with hydrated lanthanoid metal chlorides. These complexes have been characterized by elemental analysis, molar conductance, magnetic susceptibility, electronic, infrared, NMR, and mass spectral studies. Various spectral parameters have been calculated from the electronic spectra of praseodymium(III), neodymium(III), samarium(III), and dysprosium(III) complexes while the neodymium(III) complexes have been subjected to detailed investigations with respect to the hypersensitive band profile and its oscillator strength’s dependence on temperature and pH. On the basis of IR and NMR spectral studies, Hapnh is believed to act as a neutral tridentate species in the adduct complexes and as a uninegative tridentate one in the neutral complexes. Electrical conductance data indicate 1 : 1 electrolytic nature of the adducts and nonelectrolytic n..." @default.
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- W2068792204 date "1992-10-01" @default.
- W2068792204 modified "2023-09-25" @default.
- W2068792204 title "Synthetic and Spectroscopic Studies of Some Lanthanoid Metal Complexes of 2-Acetylpyridine Nicotinoylhydrazone" @default.
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- W2068792204 doi "https://doi.org/10.1246/bcsj.65.2766" @default.
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