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• W2068800241 abstract "Dinuclear gold(I) complexes [mu-(4,4'-CN-R-NC){Au(C6F4OC4H9)}2] [R = 1,4-phenylene, n = 8; R = 4,4'-biphenylene, 2,2'-dichloro-4,4'-biphenylene, 2,2'-dimethyl-4,4'-biphenylene, n = 4,6,8,10] have been prepared and their liquid crystal behavior and optical properties studied. Although the free ligands are not mesomorphic, all the gold(I) derivatives described, except the phenylisonitrilegold(I) derivative [mu-(1,4-CN-C6H4-NC){Au(C6F4OC8H17)}2], display liquid crystal behavior, giving rise to a nematic mesophase. The transition temperatures decrease in the order 4-4'-biphenylene > 2,2'-dichloro-4-4'-biphenylene > 2,2'dimethyl-4-4'-biphenylene. All compounds show photoluminescence in the solid state and in solution. The single-crystal X-ray diffraction structures of [mu-(4,4'-CN-R-NC){Au(C6F4OCnH2n+1)}2] (R = 4-4'-biphenylene and 2,2'-dichloro-4-4'-biphenylene) have been determined confirming the rodlike structure of the molecule, with a linear coordination around the gold atoms. There are Au...Au interactions in the 2,2'-dichlorobiphenyl derivative but not in the 4-4'-biphenyl compound." @default.
• W2068800241 created "2016-06-24" @default.
• W2068800241 creator A5005749039 @default.
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• W2068800241 date "2006-11-08" @default.
• W2068800241 modified "2023-10-18" @default.
• W2068800241 title "Dinuclear Gold(I) Isocyanide Complexes with Luminescent Properties, and Displaying Thermotropic Liquid Crystalline Behavior" @default.
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• W2068800241 doi "https://doi.org/10.1021/ic060702a" @default.
• W2068800241 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/17140225" @default.
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