Matches in SemOpenAlex for { <https://semopenalex.org/work/W2068822197> ?p ?o ?g. }
- W2068822197 endingPage "10847" @default.
- W2068822197 startingPage "10847" @default.
- W2068822197 abstract "The high stability of Salonen's thermally carbonized porous silicon (TCPSi) has attracted attention for environmental and biochemical sensing applications, where corrosion-induced zero point drift of porous silicon-based sensor elements has historically been a significant problem. Prepared by the high temperature reaction of porous silicon with acetylene gas, the stability of this silicon carbide-like material also poses a challenge—many sensor applications require a functionalized surface, and the low reactivity of TCPSi has limited the ability to chemically modify its surface. This work presents a simple reaction to modify the surface of TCPSi with an alkyl carboxylate. The method involves radical coupling of a dicarboxylic acid (sebacic acid) to the TCPSi surface using a benzoyl peroxide initiator. The grafted carboxylic acid species provides a route for bioconjugate chemical modification, demonstrated in this work by coupling propylamine to the surface carboxylic acid group through the intermediacy of pentafluorophenol and 1-ethyl-3-[3-dimethylaminopropyl]carbodiimide hydrochloride (EDC). The stability of the carbonized porous Si surface, both before and after chemical modification, is tested in phosphate buffered saline solution and found to be superior to either hydrosilylated (with undecylenic acid) or thermally oxidized porous Si surfaces." @default.
- W2068822197 created "2016-06-24" @default.
- W2068822197 creator A5020625628 @default.
- W2068822197 creator A5032101079 @default.
- W2068822197 creator A5043369971 @default.
- W2068822197 creator A5059375688 @default.
- W2068822197 date "2010-01-01" @default.
- W2068822197 modified "2023-10-16" @default.
- W2068822197 title "Bioconjugate functionalization of thermally carbonized porous silicon using a radical coupling reaction" @default.
- W2068822197 cites W1674507740 @default.
- W2068822197 cites W1966165751 @default.
- W2068822197 cites W1970287205 @default.
- W2068822197 cites W1971944199 @default.
- W2068822197 cites W1972170454 @default.
- W2068822197 cites W1973164515 @default.
- W2068822197 cites W1977577537 @default.
- W2068822197 cites W1983929623 @default.
- W2068822197 cites W1985261292 @default.
- W2068822197 cites W1997036124 @default.
- W2068822197 cites W2005484249 @default.
- W2068822197 cites W2006346404 @default.
- W2068822197 cites W2007097955 @default.
- W2068822197 cites W2009324867 @default.
- W2068822197 cites W2011488302 @default.
- W2068822197 cites W2020136611 @default.
- W2068822197 cites W2024478998 @default.
- W2068822197 cites W2026524260 @default.
- W2068822197 cites W2027595340 @default.
- W2068822197 cites W2027938712 @default.
- W2068822197 cites W2030330969 @default.
- W2068822197 cites W2034369160 @default.
- W2068822197 cites W2035688879 @default.
- W2068822197 cites W2044648584 @default.
- W2068822197 cites W2044674242 @default.
- W2068822197 cites W2044772849 @default.
- W2068822197 cites W2045559222 @default.
- W2068822197 cites W2047249233 @default.
- W2068822197 cites W2050501490 @default.
- W2068822197 cites W2056041344 @default.
- W2068822197 cites W2056268601 @default.
- W2068822197 cites W2063802926 @default.
- W2068822197 cites W2064408672 @default.
- W2068822197 cites W2067313136 @default.
- W2068822197 cites W2068022359 @default.
- W2068822197 cites W2068264563 @default.
- W2068822197 cites W2070185729 @default.
- W2068822197 cites W2071593273 @default.
- W2068822197 cites W2074835169 @default.
- W2068822197 cites W2075580368 @default.
- W2068822197 cites W2078819274 @default.
- W2068822197 cites W2081676858 @default.
- W2068822197 cites W2088261032 @default.
- W2068822197 cites W2089179687 @default.
- W2068822197 cites W2089595371 @default.
- W2068822197 cites W2093786378 @default.
- W2068822197 cites W2111099731 @default.
- W2068822197 cites W2122287862 @default.
- W2068822197 cites W2124923919 @default.
- W2068822197 cites W2131504798 @default.
- W2068822197 cites W2132495195 @default.
- W2068822197 cites W2155405445 @default.
- W2068822197 cites W2162946469 @default.
- W2068822197 doi "https://doi.org/10.1039/c0dt00936a" @default.
- W2068822197 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/3051409" @default.
- W2068822197 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/20967329" @default.
- W2068822197 hasPublicationYear "2010" @default.
- W2068822197 type Work @default.
- W2068822197 sameAs 2068822197 @default.
- W2068822197 citedByCount "45" @default.
- W2068822197 countsByYear W20688221972012 @default.
- W2068822197 countsByYear W20688221972013 @default.
- W2068822197 countsByYear W20688221972014 @default.
- W2068822197 countsByYear W20688221972015 @default.
- W2068822197 countsByYear W20688221972016 @default.
- W2068822197 countsByYear W20688221972017 @default.
- W2068822197 countsByYear W20688221972018 @default.
- W2068822197 countsByYear W20688221972019 @default.
- W2068822197 countsByYear W20688221972020 @default.
- W2068822197 countsByYear W20688221972021 @default.
- W2068822197 countsByYear W20688221972022 @default.
- W2068822197 crossrefType "journal-article" @default.
- W2068822197 hasAuthorship W2068822197A5020625628 @default.
- W2068822197 hasAuthorship W2068822197A5032101079 @default.
- W2068822197 hasAuthorship W2068822197A5043369971 @default.
- W2068822197 hasAuthorship W2068822197A5059375688 @default.
- W2068822197 hasBestOaLocation W20688221974 @default.
- W2068822197 hasConcept C115537861 @default.
- W2068822197 hasConcept C127413603 @default.
- W2068822197 hasConcept C150394285 @default.
- W2068822197 hasConcept C154877778 @default.
- W2068822197 hasConcept C159985019 @default.
- W2068822197 hasConcept C178790620 @default.
- W2068822197 hasConcept C185592680 @default.
- W2068822197 hasConcept C188027245 @default.
- W2068822197 hasConcept C192562407 @default.
- W2068822197 hasConcept C2776685891 @default.
- W2068822197 hasConcept C2778074193 @default.
- W2068822197 hasConcept C2779074116 @default.