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• W2068839195 abstract "A new intermolecular potential for Ne–HCl with HCl in its v=1 state is obtained by least-squares fitting to molecular-beam near-infrared laser spectra of the Ne–HCl and Ne–DCl van der Waals complexes. In agreement with previous potentials, the equilibrium geometry is found to be linear Ne–H–Cl, with a well depth around 64 cm−1. There is also a secondary minimum at the linear Ne–Cl–H geometry, with a depth around 57 cm−1, which arises because the Ne atom can approach closer to the Cl atom at the linear geometry than at a T-shaped geometry. The new potential is slightly less anisotropic than earlier potentials for HCl in its v=0 state. The fitted potential is used to calculate additional bound states of the Ne–HCl van der Waals complex, which have not yet been observed spectroscopically." @default.
• W2068839195 created "2016-06-24" @default.
• W2068839195 creator A5076915232 @default.
• W2068839195 date "1989-10-15" @default.
• W2068839195 modified "2023-10-02" @default.
• W2068839195 title "The intermolecular potential of Ne–HCl: Determination from high-resolution spectroscopy" @default.
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• W2068839195 doi "https://doi.org/10.1063/1.456781" @default.
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