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• W2068846935 abstract "The concise synthesis of rhododendrol glycosides 3-8, which are novel derivatives of (+)-epirhododendrin (1) and (-)-rhododendrin (2), has been achieved in six steps from benzaldehyde 9. The key reactions include aldol condensation and trichloroacetimidate glycosylation. From biological studies, it has been determined that synthetic derivatives of 1 and 2 possess potent tyrosinase inhibitory activity. Particularly, the inhibitory activity of cellobioside 8 (IC50=1.51μM) is six times higher than that of kojic acid. The R-epimers (4, 6, and 8) possessed more potent activity than the corresponding S-epimers (3, 5, and 7), indicating that tyrosinase inhibitory activity is significantly governed by stereochemistry of rhododendrol glycosides." @default.
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• W2068846935 date "2014-01-01" @default.
• W2068846935 modified "2023-10-12" @default.
• W2068846935 title "Chemical synthesis and tyrosinase inhibitory activity of rhododendrol glycosides" @default.
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• W2068846935 doi "https://doi.org/10.1016/j.bmcl.2013.11.063" @default.
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