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- W2068856876 abstract "Abstract Methoxy-arylacetylenic sulfones were examined to react with various carbanion nucleophiles to result in the three types of products; thus, (i) nucleophiles (MeLi·LiBr, Vinyl MgBr, LiCH2CN) showed the α-addition, however, (ii) Li–C C–TMS afforded β-addition (conjugate addition) products. The (iii) displacement reaction through α-addition/isomerization/trans-elimination was enhanced by the presence of ortho-methoxy group at high temperature. The heteroatom nucleophiles (nitrogen, oxygen or sulfur atom) in a protic solvent provided only conjugate addition products as reported." @default.
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- W2068856876 date "2011-12-01" @default.
- W2068856876 modified "2023-10-16" @default.
- W2068856876 title "Three types of products by carbon nucleophiles toward methoxyphenylacetylenic sulfones" @default.
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- W2068856876 doi "https://doi.org/10.1016/j.tet.2011.09.078" @default.
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