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- W206889632 abstract "Thiol-ene networks are readily synthesized via photopolymerization of multifunctional thiols and enes via a radical- mediated step-growth mechanism allowing a precise tailorability of physical, mechanical, thermal, and optical properties of the network. Also, delayed gelation, low shrinkage, photoinitiator-free formulations, 3 reduced oxygen inhibition and homogeneity in these polymer networks lend promise to these networks as high performance materials. But, the inherent flexibility of thioether linkages limits their application for high Tg materials. 4, 5 Thus, further improvement in mechanical properties and thermal properties are highly desirable. Polybenzoxazines are a promising class of non-halogen phenol-based thermosets which undergoes thermal ring opening polymerization without generating byproduct, thus offer an attractive alternative to traditional phenolic and epoxy resins. PBZOs exhibit inherent properties such as high glass transition temperatures, near-zero shrinkage (zero volatile byproducts), high thermal stability, excellent flame resistance (high char yields), low surface energy 6 and low water absorption. 7, 8" @default.
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- W206889632 date "2011-01-01" @default.
- W206889632 modified "2023-09-28" @default.
- W206889632 title "Development of Hybrid Dual-Cure Polymer Networks via Thiol-ene and Benzoxazine Chemistries" @default.
- W206889632 hasPublicationYear "2011" @default.
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