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- W2068901295 abstract "The steric misfit between a geminal bis(pyrazol-1-yl)propane ligand and tetrahedral coordination leads to distortion of the latter in the title compound: NZnN is 89.5(1)°, ClZnCl 116.78(5)°. Comparison of the ZnN (2.058(3), 2.046(3) A) and ZnCl (2.209(1), 2.229(1) A) distances with those of related compounds evidences the steric bulkiness of the title ligand.2,2′-Bis(pyrazol-1-yl)propan - ein voluminoser Ligand: Kristallstrukturanalyse des Adduktes mit ZinkchloridDurch den zweibindigen Liganden Bis-(pyrazol-1-yl)propan erfolgt eine sterische Behinderung zur Bildung der tetraedrischen Koordination um das Zink in der Titelverbindung, wodurch eine Verzerrung dieser Koordination erfolgt. Die Winkel NZnN und ClZnCl betragen deshalb: 89,5(1)° bzw. 116,78(5)°. Ein Vergleich der Abstande ZnN (2,058(3); 2,046(3) A) und ZnCl (2,209(1); 2,229(1) A) mit denen verwandter Verbindungen zeigt den sterischen Einflus des Titelliganden." @default.
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- W2068901295 date "1992-04-01" @default.
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- W2068901295 title "Bis(pyrazol-1-yl)propane as a bulky Ligand: X-ray Crystal Structure Determination of its Adduct with Zinc(II) Chloride" @default.
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