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- W2068926480 abstract "The Kagan MLn models developed for rationalizing non-linear effects of catalyst enantiopurity have become a valuable mechanistic tool for probing complex asymmetric catalytic reactions. This work demonstrates how these models also provide clues about reactivity that may be used for further evidence to test a mechanistic hypothesis. Special considerations for probing non-linear effects in asymmetric synthesis using stoichiometric chiral auxiliaries and in asymmetric autocatalysis are highlighted in comparison with asymmetric catalysis." @default.
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- W2068926480 date "2010-06-01" @default.
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- W2068926480 title "Kinetic aspects of non-linear effects in asymmetric synthesis, catalysis, and autocatalysis" @default.
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- W2068926480 doi "https://doi.org/10.1016/j.tetasy.2010.03.034" @default.
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