FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2068933907> ?p ?o ?g. }

• W2068933907 endingPage "8998" @default.
• W2068933907 startingPage "8993" @default.
• W2068933907 abstract "Sodium citrate reduction of hydrogen tetrachloroaurate is one of the most efficient routes in the synthesis of gold nanoparticles (AuNPs). However, a major limitation of this method is that it results only in citrate-stabilized AuNPs, and exchange reactions of the citrate for another stabilizer must be undertaken in cases where other surface functionalities are desired. These exchange reactions can be studied using a variety of techniques. Two techniques we have used for analysis are ultraviolet-visible spectroscopy, which takes advantage of the plasmon resonance (PR) of AuNPs, and liquid chromatography (LC) to examine residual exchanger in the supernatant at equilibrium. The exchange of the citrate on the surface of AuNPs with aniline was studied where different concentrations of aniline are added. While the equilibrium PR band spectra were similar for high and low concentrations of added aniline, the spectra as a function of time differed markedly. Surprisingly, increasing the concentration of added aniline slowed the evolution of a second red-shifted band. Transmission electron microscopy (TEM) imaging showed that addition of neither high nor low concentrations of aniline caused a significant difference in particle size, and the appearance of the large second band was most likely due to the presence of an oligomeric aniline species surrounding the particles. As aniline is known to undergo polymerization under a variety of conditions, it is postulated that aniline polymerization is a competitive event to the ligand exchange process, and increasing the aniline concentration increases the likelihood of polymerization kinetically competing with association of the aniline species interacting with the AuNP surface. This was further supported by LC data, which demonstrated that the aniline exchanged at approximately 4% of the initial amount of citrate present in the synthetic mixture." @default.
• W2068933907 created "2016-06-24" @default.
• W2068933907 creator A5002252291 @default.
• W2068933907 creator A5005765470 @default.
• W2068933907 date "2009-06-19" @default.
• W2068933907 modified "2023-10-17" @default.
• W2068933907 title "The Effect of Aniline Concentration in the Ligand Exchange Reaction with Citrate-Stabilized Gold Nanoparticles" @default.
• W2068933907 cites W1968044889 @default.
• W2068933907 cites W1971819583 @default.
• W2068933907 cites W1981855264 @default.
• W2068933907 cites W1989642666 @default.
• W2068933907 cites W1995981635 @default.
• W2068933907 cites W2009008819 @default.
• W2068933907 cites W2010162891 @default.
• W2068933907 cites W2011957187 @default.
• W2068933907 cites W2020790435 @default.
• W2068933907 cites W2028834783 @default.
• W2068933907 cites W2032296179 @default.
• W2068933907 cites W2033514399 @default.
• W2068933907 cites W2035728476 @default.
• W2068933907 cites W2037252212 @default.
• W2068933907 cites W2037868432 @default.
• W2068933907 cites W2042190324 @default.
• W2068933907 cites W2043009832 @default.
• W2068933907 cites W2045276693 @default.
• W2068933907 cites W2045750879 @default.
• W2068933907 cites W2046890061 @default.
• W2068933907 cites W2055702261 @default.
• W2068933907 cites W2062470136 @default.
• W2068933907 cites W2067712937 @default.
• W2068933907 cites W2071224672 @default.
• W2068933907 cites W2077228161 @default.
• W2068933907 cites W2078954120 @default.
• W2068933907 cites W2079753165 @default.
• W2068933907 cites W2081079273 @default.
• W2068933907 cites W2086467764 @default.
• W2068933907 cites W2087572685 @default.
• W2068933907 cites W2091729786 @default.
• W2068933907 cites W2093018348 @default.
• W2068933907 cites W2107519814 @default.
• W2068933907 cites W2112165279 @default.
• W2068933907 cites W2115029038 @default.
• W2068933907 cites W2122374845 @default.
• W2068933907 cites W2127782510 @default.
• W2068933907 cites W2128469407 @default.
• W2068933907 cites W2131430454 @default.
• W2068933907 cites W2135308128 @default.
• W2068933907 cites W2162034088 @default.
• W2068933907 cites W2167152367 @default.
• W2068933907 cites W4234635936 @default.
• W2068933907 cites W4247230477 @default.
• W2068933907 doi "https://doi.org/10.1021/la900680e" @default.
• W2068933907 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/19537821" @default.
• W2068933907 hasPublicationYear "2009" @default.
• W2068933907 type Work @default.
• W2068933907 sameAs 2068933907 @default.
• W2068933907 citedByCount "11" @default.
• W2068933907 countsByYear W20689339072013 @default.
• W2068933907 countsByYear W20689339072014 @default.
• W2068933907 countsByYear W20689339072015 @default.
• W2068933907 countsByYear W20689339072016 @default.
• W2068933907 countsByYear W20689339072017 @default.
• W2068933907 countsByYear W20689339072018 @default.
• W2068933907 countsByYear W20689339072019 @default.
• W2068933907 crossrefType "journal-article" @default.
• W2068933907 hasAuthorship W2068933907A5002252291 @default.
• W2068933907 hasAuthorship W2068933907A5005765470 @default.
• W2068933907 hasConcept C104819515 @default.
• W2068933907 hasConcept C106847996 @default.
• W2068933907 hasConcept C116569031 @default.
• W2068933907 hasConcept C127413603 @default.
• W2068933907 hasConcept C155672457 @default.
• W2068933907 hasConcept C170493617 @default.
• W2068933907 hasConcept C178790620 @default.
• W2068933907 hasConcept C179104552 @default.
• W2068933907 hasConcept C185592680 @default.
• W2068933907 hasConcept C2779244968 @default.
• W2068933907 hasConcept C42360764 @default.
• W2068933907 hasConcept C44228677 @default.
• W2068933907 hasConcept C521977710 @default.
• W2068933907 hasConcept C55493867 @default.
• W2068933907 hasConcept C75473681 @default.
• W2068933907 hasConceptScore W2068933907C104819515 @default.
• W2068933907 hasConceptScore W2068933907C106847996 @default.
• W2068933907 hasConceptScore W2068933907C116569031 @default.
• W2068933907 hasConceptScore W2068933907C127413603 @default.
• W2068933907 hasConceptScore W2068933907C155672457 @default.
• W2068933907 hasConceptScore W2068933907C170493617 @default.
• W2068933907 hasConceptScore W2068933907C178790620 @default.
• W2068933907 hasConceptScore W2068933907C179104552 @default.
• W2068933907 hasConceptScore W2068933907C185592680 @default.
• W2068933907 hasConceptScore W2068933907C2779244968 @default.
• W2068933907 hasConceptScore W2068933907C42360764 @default.
• W2068933907 hasConceptScore W2068933907C44228677 @default.
• W2068933907 hasConceptScore W2068933907C521977710 @default.
• W2068933907 hasConceptScore W2068933907C55493867 @default.
• W2068933907 hasConceptScore W2068933907C75473681 @default.
• W2068933907 hasIssue "16" @default.

• next