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- W2068946446 abstract "Chiral substrate analogues assist in the enantioselective epoxidation of styrene catalyzed by H2O2-dependent cytochrome P450SPα. In their Full Paper on page 2286 ff., Yoshihito Watanabe et al. report that the stereoselectivity of styrene oxide is largely affected by the chirality of the substrate analogues and that (R)-ibuprofen greatly enhances the formation of (S)-styrene oxide, thus showing that ibuprofen works as a chiral inducer. This unique strategy using the chiral substrate analogues allows for the alteration of the enantioselectivity of enzymes without any mutagenesis and thus contributes to the development of novel asymmetric biocatalysts. Gold-catalyzed reactions involving chirality transfer and memory of chirality (MOC) have emerged as a powerful tool for enantioselective synthesis. In the Focus Review on page 2186 ff., Nitin T. Patil discusses this emerging field with emphasis on mechanistic aspects and covering applications in synthetic organic chemistry.1 Photochemistry In their Full Paper on page 2240 ff., Kazumitsu Kawakami and Akihiko Tsuda report on the development of photochemical generations of elemental Br2 from brominated methanes. They demonstrate that liquid brominated methanes such as CH2Br2 and CHBr3 can be used not only as organic solvents but also for the photoresponsive molecular storage of Br2, which is of great technical benefit in a variety of organic syntheses and in materials science. By taking advantage of the in situ generation of Br2 from the organic solvent itself, many organobromine compounds could be easily synthesized in high yields. Further, CH2Br2 allows the area-selectable photochemical bleaching of colored natural materials such as rose petals.1" @default.
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- W2068946446 date "2012-09-17" @default.
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- W2068946446 title "Cover Picture: Chiral-Substrate-Assisted Stereoselective Epoxidation Catalyzed by H2O2-Dependent Cytochrome P450SPα(Chem. Asian J. 10/2012)" @default.
- W2068946446 doi "https://doi.org/10.1002/asia.201290039" @default.
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