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- W2068946586 abstract "A unique coordination polymer, {[CuLNa(ClO4)]·H2O}n (1), was isolated from the solution containing sodium perchlorate and the neutral macrocyclic oxamidocopper(II) complex [CuL] (H2L = 2,3-dioxo-5,6:13, 14-dibenzo-7, 12-bis(ethoxycarbonyl)-1, 4, 8, 11-tetraazacyclotetradeca-7, 11-diene). The complex is composed of [Na2Cu2] tetrametallacycles bridged by perchlorate ions to form infinite one-dimensional chains which are stacked via τ-τ interactions and weak coordination bonds to result in a two-dimensional supramolecular network. The perclorate ions were found to coordinate to sodium atoms in the unusual bridging chelating tridentate mode of μ2-(O:O′,O″)." @default.
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- W2068946586 date "2010-08-26" @default.
- W2068946586 modified "2023-09-28" @default.
- W2068946586 title "Synthesis and Crystal Structure of a One-Dimensional Coordination Polymer Containing Unusual Na2Cu2 Tetrametallacyclic Units" @default.
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- W2068946586 doi "https://doi.org/10.1002/cjoc.20020200811" @default.
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