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- W2068956843 abstract "The system ZnO-Ti02 has been investigated using quenching, hydrothermal, strip-furnace, and solid-state-reaction techniques. Two compounds were found: Zn2Ti04, which melts congruently at 1549 C., and ZnTiO2, which dissociates hydrothermally at 945° C. to give Zn2Ti04and rutile. Two eutectics were found: one between ZnO and Zn2Ti04 at 32 mole % TiO, and 1537°C. and the other between Zn2TiO4and TiO2 at 58 mole % TiO2 and 1418°C. Rutile was the only modification of TiO2 observed. The reported melting points of ZnO and TiO2 are 1975° and 1830°C. respectively; however, data exist which indicate the sublimation of ZnO at atmospheric pressure. Loss of ZnO by volatilization slightly decreased the accuracy of the liquidus relations. Reported solid solutions of TiO2 in Zn2Ti04 and ZnTiO3 were not encountered, and explanations of this discrepancy are proposed." @default.
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- W2068956843 date "1960-03-01" @default.
- W2068956843 modified "2023-10-02" @default.
- W2068956843 title "Phase Equilibria in the System ZnO-TiO2" @default.
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- W2068956843 doi "https://doi.org/10.1111/j.1151-2916.1960.tb14326.x" @default.
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