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- W2068961191 abstract "Abstract The electroreductive chemistry of free base and metal-substituted 2,3,7,8,12,13,17,18-octakis(methylthio)tetraazaporphyrins has been investigated in pyridine at a Pt electrode. The free base, Mg, Ni, Cu and Zn derivatives were electroreduced in three discrete one-electron transfers. For all five complexes, electroreduction produced mono-, di- and tri-aniomic complexes with an enrichment of electron density on the macrocyclic ring. For the Co derivative, electron transfer reactions involving both the central metal atom and the macrocyclic ring were observed. Electron transfer pathways are proposed based upon voltammetric, coulometric and spectroelectrochemical results." @default.
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- W2068961191 date "1986-02-01" @default.
- W2068961191 modified "2023-10-16" @default.
- W2068961191 title "The electroreduction of several metallo-octakis(methylthio)tetraazaporphyrins" @default.
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- W2068961191 doi "https://doi.org/10.1016/0022-0728(86)90009-4" @default.
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