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• W2068965588 abstract "Sum-frequency generation (SFG) vibrational spectroscopy was used to study how side alkyl chains of a polyimide are oriented at the air–polymer interface and how they are affected by mechanical rubbing and adsorption of a liquid crystal monolayer. The spectra of polyimides with various alkyl chain lengths all indicate that the chains protrude out of the polyimide surface with a very broad distribution. Longer alkyl chains appear to contain more gauche defects. While the polyimide backbones are aligned by rubbing, the side chain orientation is hardly affected. Adsorption of a liquid crystal monolayer on the surface significantly reduces the gauche defects in the alkyl chains." @default.
• W2068965588 created "2016-06-24" @default.
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• W2068965588 date "2000-11-15" @default.
• W2068965588 modified "2023-10-18" @default.
• W2068965588 title "Sum-frequency generation (SFG) vibrational spectroscopy of side alkyl chain structures of polyimide surfaces" @default.
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• W2068965588 doi "https://doi.org/10.1063/1.1318199" @default.
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