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• W2068971259 abstract "Three new Cd(II) polymers [Cd2(L240)2I4]n (1), [Cd(L240)(SCN)2]n (2), and [Cd(L240)(N3)2]n (3) have been synthesized via the reaction of 3-phenyl-5-(2-pyridyl)-4-(4-pyridyl)-4H-1,2,4-triazole (L240) with CdI2 or in the presence of distinct pseudohalide anions (SCN− and N3−). Single-crystal X-ray diffraction indicates that complex 1 features a 1D coordination chain and further forms a 2D supramolecular network extended via π⋯π stacking interactions. Complex 2 shows a 2D layered coordination network and complex 3 has a 3D diamond framework. In complexes 1–3, the CdII centers adopt the same octahedral geometry, whereas the L240 ligands show distinct (μ3, η2), (μ4, η3), and (μ2, η2) binding modes, respectively. These results reveal that such polymeric networks can be well modulated by the halide anion (I−) and pseudohalide anions of SCN− and N3−. Thermal stability and fluorescence for complexes 1–3 have been studied." @default.
• W2068971259 created "2016-06-24" @default.
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• W2068971259 date "2015-05-01" @default.
• W2068971259 modified "2023-09-27" @default.
• W2068971259 title "Halide/pseudohalide-directed cadmium(II) coordination polymers based on 3-phenyl-5-(2-pyridyl)-4-(4-pyridyl)-4H-1,2,4-triazole" @default.
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• W2068971259 doi "https://doi.org/10.1016/j.poly.2015.03.001" @default.
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