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• W2068973090 startingPage "6586" @default.
• W2068973090 abstract "Li and Mg are pesky: A catalytic asymmetric synthesis of α-(hydroxyalkyl)-tri-n-butylstannanes (1) in good to excellent yields and enantioselectivities was achieved (see scheme; PG=protecting group; L*=chiral ligand). Compound 1 was isolated as an ester or thiocarbamate, and the reagent was prepared from equimolar amounts of nBu3SnH and Et2Zn in dimethoxyethane. Conditions employing lithium or magnesium ions suppress enantioselectivity." @default.
• W2068973090 created "2016-06-24" @default.
• W2068973090 creator A5007513995 @default.
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• W2068973090 date "2008-08-11" @default.
• W2068973090 modified "2023-10-18" @default.
• W2068973090 title "Synthesis of Enantioenriched α-(Hydroxyalkyl)-tri-<i>n</i>-butylstannanes" @default.
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• W2068973090 doi "https://doi.org/10.1002/anie.200802313" @default.
• W2068973090 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/3436603" @default.
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