FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2068974142> ?p ?o ?g. }

• W2068974142 endingPage "1197" @default.
• W2068974142 startingPage "1197" @default.
• W2068974142 abstract "The reactions CH3+ NO3→ products (1), and CH3O + NO3→ products (2), have been studied using a flow system at T= 298 K and at pressures between 0.6 and 8.5 Torr. The laser-induced fluorescence (LIF) technique was used to detect CH3O and multi-pass optical absorption to detect NO3. The chemical systems were studied as a pair of consecutive reactions; however, a simple analytical treatment was not sufficient to describe them because CH3O2 was formed as one of the products in the major channel of reaction (2). This species also reacts with NO3 regenerating CH3O. Use of a numerical model to correct for this regeneration process allowed rate parameters of k1=(3.5 ± 1.0)× 10–11 cm3 molecule–1 s–1 and k2=(2.3 ± 0.7)× 10–12 cm3 molecule–1 s–1 to be determined at 2.4 Torr. There is no pressure dependence observed for reaction (1) between 1 and 2.4 Torr, but the possibility of a slight pressure dependence for reaction (2) exists. These pressure effects are examined using the semi-empirical quantum RRK method." @default.
• W2068974142 created "2016-06-24" @default.
• W2068974142 creator A5027161191 @default.
• W2068974142 creator A5027588282 @default.
• W2068974142 creator A5036688084 @default.
• W2068974142 creator A5041721477 @default.
• W2068974142 creator A5042396858 @default.
• W2068974142 date "1994-01-01" @default.
• W2068974142 modified "2023-09-26" @default.
• W2068974142 title "Investigation into the kinetics and mechanism of the reaction of NO3 with CH3 and CH3O at 298 K between 0.6 and 8.5 Torr: is there a chain decomposition mechanism in operation?" @default.
• W2068974142 cites W1968396398 @default.
• W2068974142 cites W1978817134 @default.
• W2068974142 cites W1982955133 @default.
• W2068974142 cites W1996622405 @default.
• W2068974142 cites W2004246166 @default.
• W2068974142 cites W2015610845 @default.
• W2068974142 cites W2029101044 @default.
• W2068974142 cites W2050283731 @default.
• W2068974142 cites W2064052028 @default.
• W2068974142 cites W2086192758 @default.
• W2068974142 cites W2108398773 @default.
• W2068974142 cites W2142148187 @default.
• W2068974142 cites W301458204 @default.
• W2068974142 cites W2955911663 @default.
• W2068974142 doi "https://doi.org/10.1039/ft9949001197" @default.
• W2068974142 hasPublicationYear "1994" @default.
• W2068974142 type Work @default.
• W2068974142 sameAs 2068974142 @default.
• W2068974142 citedByCount "25" @default.
• W2068974142 countsByYear W20689741422012 @default.
• W2068974142 countsByYear W20689741422014 @default.
• W2068974142 countsByYear W20689741422017 @default.
• W2068974142 crossrefType "journal-article" @default.
• W2068974142 hasAuthorship W2068974142A5027161191 @default.
• W2068974142 hasAuthorship W2068974142A5027588282 @default.
• W2068974142 hasAuthorship W2068974142A5036688084 @default.
• W2068974142 hasAuthorship W2068974142A5041721477 @default.
• W2068974142 hasAuthorship W2068974142A5042396858 @default.
• W2068974142 hasConcept C113196181 @default.
• W2068974142 hasConcept C120665830 @default.
• W2068974142 hasConcept C121332964 @default.
• W2068974142 hasConcept C124681953 @default.
• W2068974142 hasConcept C125287762 @default.
• W2068974142 hasConcept C147789679 @default.
• W2068974142 hasConcept C148898269 @default.
• W2068974142 hasConcept C159985019 @default.
• W2068974142 hasConcept C161790260 @default.
• W2068974142 hasConcept C168931907 @default.
• W2068974142 hasConcept C175113610 @default.
• W2068974142 hasConcept C178790620 @default.
• W2068974142 hasConcept C185592680 @default.
• W2068974142 hasConcept C192562407 @default.
• W2068974142 hasConcept C30646810 @default.
• W2068974142 hasConcept C32909587 @default.
• W2068974142 hasConcept C36663273 @default.
• W2068974142 hasConcept C62520636 @default.
• W2068974142 hasConcept C65024703 @default.
• W2068974142 hasConcept C75473681 @default.
• W2068974142 hasConcept C91881484 @default.
• W2068974142 hasConcept C93391505 @default.
• W2068974142 hasConcept C97355855 @default.
• W2068974142 hasConceptScore W2068974142C113196181 @default.
• W2068974142 hasConceptScore W2068974142C120665830 @default.
• W2068974142 hasConceptScore W2068974142C121332964 @default.
• W2068974142 hasConceptScore W2068974142C124681953 @default.
• W2068974142 hasConceptScore W2068974142C125287762 @default.
• W2068974142 hasConceptScore W2068974142C147789679 @default.
• W2068974142 hasConceptScore W2068974142C148898269 @default.
• W2068974142 hasConceptScore W2068974142C159985019 @default.
• W2068974142 hasConceptScore W2068974142C161790260 @default.
• W2068974142 hasConceptScore W2068974142C168931907 @default.
• W2068974142 hasConceptScore W2068974142C175113610 @default.
• W2068974142 hasConceptScore W2068974142C178790620 @default.
• W2068974142 hasConceptScore W2068974142C185592680 @default.
• W2068974142 hasConceptScore W2068974142C192562407 @default.
• W2068974142 hasConceptScore W2068974142C30646810 @default.
• W2068974142 hasConceptScore W2068974142C32909587 @default.
• W2068974142 hasConceptScore W2068974142C36663273 @default.
• W2068974142 hasConceptScore W2068974142C62520636 @default.
• W2068974142 hasConceptScore W2068974142C65024703 @default.
• W2068974142 hasConceptScore W2068974142C75473681 @default.
• W2068974142 hasConceptScore W2068974142C91881484 @default.
• W2068974142 hasConceptScore W2068974142C93391505 @default.
• W2068974142 hasConceptScore W2068974142C97355855 @default.
• W2068974142 hasIssue "9" @default.
• W2068974142 hasLocation W20689741421 @default.
• W2068974142 hasOpenAccess W2068974142 @default.
• W2068974142 hasPrimaryLocation W20689741421 @default.
• W2068974142 hasRelatedWork W182153807 @default.
• W2068974142 hasRelatedWork W1964687069 @default.
• W2068974142 hasRelatedWork W1967788951 @default.
• W2068974142 hasRelatedWork W1977922539 @default.
• W2068974142 hasRelatedWork W1989280951 @default.
• W2068974142 hasRelatedWork W2161636363 @default.
• W2068974142 hasRelatedWork W2354653259 @default.
• W2068974142 hasRelatedWork W2440162759 @default.
• W2068974142 hasRelatedWork W2549373318 @default.
• W2068974142 hasRelatedWork W4232459072 @default.

• next