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- W2069101467 abstract "The effect of variations in water content on the transformation range properties of 25Na2O25Al2O350SiO2, 10Na2O10CaO20Al2o360SiO2, 20CaO20Al2O360SiO2, and 20Y2O320Al2O360SiO2 glasses are presented. Samples of these glasses were prepared with a range of water of hydroxyl contents by melting under various partial pressures of water. With an increase in water content of each glass, a decrease in both the glass transformation temperature, Tg, and the transformation range viscosity are observed. The magnitude of these effects of water depends strongly on composition and is correlated with the activation energy for viscous flow. The data from this study are combined with the known effects of water on the properties of phosphate, borate, heavy metal fluoride, and other silicate glasses to show that the flow properties of ‘strong’ liquids are affected much more dramatically than those of ‘fragile’ liquids. These data are used to determine a quantitative empirical relationship between the magnitude of the effect of water on flow properties and the fragility of the glass-forming liquid." @default.
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- W2069101467 date "1993-01-01" @default.
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- W2069101467 title "Effects of water content on aluminosilicate glasses and the relation to strong/fragile liquid theory" @default.
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- W2069101467 doi "https://doi.org/10.1016/0022-3093(93)90441-y" @default.
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