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- W2069113369 abstract "Furoin thiosemicarbazone (FTS) reacts with Ni(II), Pd(II) and Cu(II) in aqueous medium, giving yellow solutions at pH 9, 6 and 3 respectively. The complexes have absorption maxima at 360 nm for Ni(II) and Pd(II) and 355 nm for Cu(II). At these wavelengths the reagent absorbance is negligible. The molar absorptivities are 1.54 × 104 [Ni(FTS)2], 1.98 × 104 [Pd(FTS)2] and 1.45 × 104 1.mole−1.cm−1 (CuFTS). Beer's law is valid up to 4, 5 and 3 ppm for Ni, Pd and Cu respectively. The apparent instability constant of the Ni—FTS system is found to be 6.5 × 10−11, of the Cu—FTS system 7.1 × 10−7 and of the Pd—FTS system 3 × 10−12 at the recommended pH values. The effect of various ions is reported." @default.
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- W2069113369 date "1978-09-01" @default.
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- W2069113369 title "Furoin thiosemicarbazone as an analytical reagent for nickel(II), palladium(II) and copper(II)" @default.
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- W2069113369 doi "https://doi.org/10.1016/0039-9140(78)80096-4" @default.
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