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- W2069123512 abstract "Biological systems synthesize proteins with an almost exclusive use of L-amino acids and virtually none of the D isomer. There has been no satisfactory explanation for the origin of this use of the L isomer. Research presented here shows that at pH 5, transfer of phenylalanine from the adenylate anhydride to ester occurs and is 95-97% efficient for the L isomer and only about 50% efficient for the D isomer. The origin of the use of the L isomer, given D-ribose nucleotides, may be based in part on this stereoselectivity." @default.
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- W2069123512 date "1991-03-19" @default.
- W2069123512 modified "2023-09-25" @default.
- W2069123512 title "Stereoselective, nonenzymic, intramolecular transfer of amino acids" @default.
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- W2069123512 doi "https://doi.org/10.1021/bi00225a005" @default.
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