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• W2069127533 abstract "Large basis set configuration interaction calculations yield an electron affinity of 0.42 eV for CH2(3B1). Application of an empirical correction, based on the known deficiencies of the basis set and CI method in atomic calculations, suggests that this estimate should be increased to approximately 0.63 eV. This provides futher evidence in favor of a reinterpretation of the photoelectron spectrum work of Zittel et al., which indicated an electron affinity of only 0.210 eV while giving a 3B1–1A1 energy gap of 19.6 kcal/mol." @default.
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• W2069127533 date "1982-12-15" @default.
• W2069127533 modified "2023-09-23" @default.
• W2069127533 title "A theoretical determination of the electron affinity of methylene" @default.
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• W2069127533 doi "https://doi.org/10.1063/1.443858" @default.
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