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- W2069127968 abstract "The identification of Ir4 and Ir6 as catalytically active species is reported. Supported metal carbonyl clusters, [Ir4(CO)12]/γ-Al2O3, [Ir6(CO)15]2−/γ-Al2O3, and [HIr4(CO)11]−/MgO, were treated in He to prepare supported metal clusters modeled as Ir4/γ-Al2O3 (1), Ir6/γ-Al2O3 (2), and Ir4/MgO (3). The samples were characterized by extended X-ray absorption fine structure (EXAFS) spectroscopy during propene hydrogenation catalysis; the partial pressures of propene and hydrogen were both 0.5 bar. From the EXAFS data the Ir-Ir shell coordination numbers of 1, 2, and 3 were determined as 3.2, 4.0, and 3.0, respectively." @default.
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- W2069127968 date "1999-07-22" @default.
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- W2069127968 title "Supported Iridium Cluster Catalysts for Propene Hydrogenation: Identification by X-Ray Absorption Spectra Measured During Catalysis" @default.
- W2069127968 doi "https://doi.org/10.1002/(sici)1521-3765(19990802)5:8<2417::aid-chem2417>3.0.co;2-g" @default.
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