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- W2069177910 abstract "We use arrested-flow pulse broadening to measure the diffusion coefficients of four archetype organic semiconductors in two carrier gases, N2 and Ar, with a precision of 5%. The measurements are realized by the injection and transport of pulses of organic molecules in an organic vapor phase deposition chamber, followed by their detection using laser induced fluorescence that dynamically measures the organic concentration in the gas phase. Measurements show that the diffusivity of tris(8-hydroxyquinoline) aluminum (Alq3) in N2 and Ar varies as the square of the temperature and inversely with pressure over a large range of gas conditions. We show that classical Chapman-Enskog theory can be used to approximate the diffusivity with an accuracy that depends on the physical dimensions of the organic molecular species, with the most accurate predictions for spherical and rigid molecules such as Alq3." @default.
- W2069177910 created "2016-06-24" @default.
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- W2069177910 date "2013-07-22" @default.
- W2069177910 modified "2023-09-27" @default.
- W2069177910 title "Diffusion coefficients of fluorescent organic molecules in inert gases" @default.
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- W2069177910 doi "https://doi.org/10.1063/1.4816960" @default.
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