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- W2069180552 abstract "The room-temperature electrical resistivity of Fe2O3 (hematite) has been measured to 61 GPa in the diamond-anvil cell. At 48 (+−2) GPa, the resistivity decreases from 0.5 ohm-m to 3(+−2) × 10−4 ohm-m. This discontinuity in resistivity is coincident with a structural phase transformation that has previously been documented in static-compression and shock-wave experiments on Fe2O3. We propose that the transition involves a change in electronic transport mechanism, possibly from d-band conduction to electronic hopping between iron ions of differing valence. The quantitative agreement for Fe2O3 between our static measurements and existing shock-wave measurements of electrical resistivity provides the first confirmation that both techniques probe the same phase of Fe2O3 at ultrahigh pressures." @default.
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- W2069180552 date "1986-04-01" @default.
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- W2069180552 title "High-pressure electrical resistivity measurements of Fe2O3: Comparison of static-compression and shock-wave experiments to 61 GPa" @default.
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- W2069180552 doi "https://doi.org/10.1016/0038-1098(86)90869-0" @default.
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