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• W2069198624 abstract "Na2MnSi4O10 has been hydrothermally synthesized from gel kept in a Teflon-lined autoclave at 225°C for 10 days. Its $$P bar{1} $$ crystal structure has been solved from single-crystal X-ray diffraction data and anisotropically refined to R = 0.025. Being the structure isotypic with that of NaKMnSi4O10 (manaksite), it is referred to a manaksite-like cell (a = 6.946 Å, b = 7.846 Å, c = 9.974 Å, α = 106.21°, β = 98.54°, γ = 115.74°) instead than to its reduced cell (a = 6.946 Å, b = 7.846 Å, c = 9.885 Å, α = 101.94°, β = 102.02°, γ = 115.74°). The Na+ cation corresponding to K+ in manaksite is split on two positions. All known AA′MSi4O10 structures are triclinic, but show a strong monoclinic character. They are based on tubes delimited by elliptical six-membered rings of SiO4 tetrahedra and connected, to form a heteropolyhedral framework, by dimeric units consisting of two edge-sharing tetragonal pyramids of M-coordination polyhedra. A and A′ cations are located in the silicate tubes and in channels that are delimited by four tetrahedra and two dimeric units. The bottlenecks of tubes and channels are however, too narrow to define the structure as microporous." @default.
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• W2069198624 date "2011-04-13" @default.
• W2069198624 modified "2023-09-29" @default.
• W2069198624 title "Synthesis and crystal structure of Na2MnSi4O10: relationship with the manaksite group" @default.
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• W2069198624 doi "https://doi.org/10.1007/s12210-011-0125-5" @default.
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