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• W2069236495 abstract "We describe here an electrochemical cell ideal for routine analysis of CE-EC experiments (capillary electrophoresis coupled with electrochemical detection). The cell was modified from a fiber-optic connector, named MT, which allowed frequent change and fast alignment between a pair of 4-strand fiber ribbons. The relative standard deviations of the current response and migration time for 100 microM dopamine were, respectively, 3.7 and 0.5% in five repetitive routines of disconnecting, polishing, and assembling the CE cell. The time required for alignment of the separation capillary and the working electrode was < 10 s, once all components were assembled in an MT fiber-optic plug. These features enabled CE-EC users to polish the working electrode and reassemble the EC cell as in HPLC-EC. However, to accommodate the channel dimensions of the commercially available MT, a special order capillary with outer diameter of 125 microm is necessary at this stage." @default.
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• W2069236495 date "2002-06-01" @default.
• W2069236495 modified "2023-09-24" @default.
• W2069236495 title "Capillary−Electrode Alignment by an Optical-Fiber Connector for Amperometric Detection in Capillary Electrophoresis" @default.
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• W2069236495 doi "https://doi.org/10.1021/ac025679z" @default.
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