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- W2069275880 abstract "Abstract Studies have been completed of the reactions involved with arsenic and antimony additives in H 2 O 2 flames and H 2 O 2 flames seeded with potassium. The flame was atmospheric and a molecular beam of the frozen species was introduced into the mass spectrometer through a four-stage differential pumping system operating from 1 to 10−11 atm. Arsenic compounds found in the flame included AsO(g), HAsO3(g) and H3AsO4(g). Heat of formation values, ΔHf298, were calculated as −145.4±5 kcal/mole for HAsO3(g) and −259.7±5 kcal/mole for H3AsO4(g). Antimony compounds included Sb(g), SbO(g), HSbO3(g) and H3SbO4(g), yielding ΔHf298 values of 18.7±5 kcal/mole for SbO(g), −137.4±5 kcal/mole for HSbO3(g), and −262.9±5 kcal/mole for H3SbO4(g). The formation of the potassium compounds KH2AsO4(g) and KH2SbO4(g) was also established. Heats of formation values, ΔHf298, obtained for the K-substituted compounds were −299.5±5 and −303.7±5 kcal/mole for KH2AsO4(g) and KH2SbO4(g), respectively." @default.
- W2069275880 created "2016-06-24" @default.
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- W2069275880 date "1975-08-01" @default.
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- W2069275880 title "An investigation of arsenic and antimony additives in unseeded and potassium-seeded H2O2 flames" @default.
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- W2069275880 doi "https://doi.org/10.1016/0010-2180(75)90073-5" @default.
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