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• W2069284962 startingPage "340" @default.
• W2069284962 abstract "A novel chiral purely organic crystal [(A)(HA+HSO4−)2]⋅2H2O (1) (A = 2-(imidazo [1,2-a]pyridin-2-yl)-2-oxoacetic acid) has been obtained through diffusion of acetone into sulfuric acid aqueous solution of A. This crystal was characterized by the elemental analysis, IR spectrum and the single crystal X-ray diffraction. Compound 1 crystallizes in the monoclinic system, chiral space group P21, with a = 10.092(2) Å, b = 15.641(3) Å, c = 10.551(2) Å, β = 101.62(3)°, and Z = 2. Compound 1 reveals left-handed 21 helical chain assembled by hydrogen bond and hydrophobic (short atomic contact) interactions, in which spontaneous resolution occurs. The left-handed chirality of the original helical chain is transferred uniformly to adjacent chain in a homochiral manner, through interchain hydrogen bond and hydrophobic interactions, resulting in the formation of chiral layer. Compound 1 also exhibits green phosphorescence." @default.
• W2069284962 created "2016-06-24" @default.
• W2069284962 creator A5036367432 @default.
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• W2069284962 date "2015-03-01" @default.
• W2069284962 modified "2023-09-25" @default.
• W2069284962 title "Spontaneous resolution in a new chiral purely organic crystal containing homochiral helical chains: Synthesis, crystal structure, and phosphorescence" @default.
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• W2069284962 doi "https://doi.org/10.1016/j.molstruc.2014.12.057" @default.
• W2069284962 hasPublicationYear "2015" @default.
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