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- W2069285502 abstract "Allene reacts with the benzothiazolide clusters [Os 3 (CO) 9 (μ 3 -NSC 7 H 3 R)(μ-H)] (R = H, Me) to afford the bridging allyl complexes [Os 3 (CO) 7 (μ-CO) 2 (μ-NSC 7 H 3 R)(μ-η 1 :η 2 :η 1 -CH 2 CHCH 2 )] resulting from insertion of allene into the metal–hydride. Both have been crystallographically characterized and differ with respect to the relative arrangement of allyl and benzothiazolide at the triosmium centre. Reactivity of electron-deficient triosmium benzothiazolide clusters towards allene is investigated. ► Reactions of electron-deficient triosmium-hydride clusters with allene. ► Insertion of allene into metal–hydride. ► Formation of bridging allyl ligand." @default.
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- W2069285502 date "2011-09-01" @default.
- W2069285502 modified "2023-09-24" @default.
- W2069285502 title "Bridging allyl ligands upon allene insertion into electron-deficient triosmium-hydride clusters [Os3(CO)9(μ3-NSC7H3R)(μ-H)] (R = H, Me)" @default.
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- W2069285502 doi "https://doi.org/10.1016/j.jorganchem.2011.04.024" @default.
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