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- W2069311936 abstract "Reactions of the compounds Me3MCl (M = Si or Sn) and Me3GeBr with diethyl ether solutions obtained by treating bromocyclo-octatetraene with n-butyl-lithium at –80 °C afford the monosubstituted cyclo-octatetraene compounds C8H7MMe3. The complex [Fe(CO)2(C8H7)(η-C5H5)] has been similarly prepared from [FeCl-(CO)2(η-C5H5)]. These cyclo-octatetraene derivatives react with enneacarbonyldi-iron to yield complexes of the tricarbonyliron group; the silicon and tin derivatives also form binuclear iron complexes [Fe2(CO)6(C8H7-MMe3)]. The complexes [Fe(CO)3(C8H7MMe3)](M = Si or Ge) react with Ph3CBF4 to yield tetrafluoroborate salts which on hydrolysis give complexes [Fe(CO)3{C8H6(MMe3)(CPh3)}] containing disubstituted cyclo-octatetraene ligands." @default.
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- W2069311936 date "1975-01-01" @default.
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- W2069311936 title "Chemistry of the metal carbonyls. Part LXX. Trimethylsilyl, trimethylgermyl, and trimethylstannyl derivatives of cyclo-octatetraene and their complexes with the tricarbonyliron group" @default.
- W2069311936 doi "https://doi.org/10.1039/dt9750000256" @default.
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