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- W2069339876 endingPage "014901" @default.
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- W2069339876 abstract "Hydrogenation of cyclohexanecarboxamide to aminomethylcyclohexane was conducted with silica-supported bimetallic catalysts composed of noble metal and group 6-7 elements. The combination of rhodium and molybdenum with molar ratio of 1:1 showed the highest activity. The effect of addition of various metal oxides was investigated on the catalysis of Rh-MoO x /SiO2, and the addition of CeO2 much increased the activity and selectivity. Higher hydrogen pressure and higher reaction temperature in the tested range of 2-8 MPa and 393-433 K, respectively, were favorable in view of both activity and selectivity. The highest yield of aminomethylcyclohexane obtained over Rh-MoO x /SiO2 + CeO2 was 63%. The effect of CeO2 addition was highest when CeO2 was not calcined, and CeO2 calcined at >773 K showed a smaller effect. The use of CeO2 as a support rather decreased the activity in comparison with Rh-MoO x /SiO2. The weakly-basic nature of CeO2 additive can affect the surface structure of Rh-MoO x /SiO2, i.e. reducing the ratio of Mo-OH/Mo-O- sites." @default.
- W2069339876 created "2016-06-24" @default.
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- W2069339876 date "2015-02-25" @default.
- W2069339876 modified "2023-10-12" @default.
- W2069339876 title "Combination of supported bimetallic rhodium–molybdenum catalyst and cerium oxide for hydrogenation of amide" @default.
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- W2069339876 doi "https://doi.org/10.1088/1468-6996/16/1/014901" @default.
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